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Determine whether or not each redox reaction occurs spontaneously in the forward direction.
(a) C a2+(aq)+Zn(s)⟶Ca(s)+Zn2+(aq)\mathrm{Ca}^{2+}(a q)+\mathrm{Zn}(s) \longrightarrow \mathrm{Ca}(s)+\mathrm{Zn}^{2+}(a q)
(b) 2A g+(aq)+Ni(s)⟶2Ag(s)+Ni2+(aq)2 \mathrm{Ag}^{+}(a q)+\mathrm{Ni}(s) \longrightarrow 2 \mathrm{Ag}(s)+\mathrm{Ni}^{2+}(a q)
(c) Fe(s)+Mn2+(aq)⟶Fe2+(aq)+Mn(s)\mathrm{Fe}(s)+\mathrm{Mn}^{2+}(a q) \longrightarrow \mathrm{Fe}^{2+}(a q)+\mathrm{Mn}(s)
(d) 2Al(s)+3 Pb2+(aq)⟶2Al3+( aq)+3 Pb(s)2 \mathrm{Al}(s)+3 \mathrm{~Pb}^{2+}(a q) \longrightarrow 2 \mathrm{Al}^{3+}(a q)+3 \mathrm{~Pb}(s)
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